‘Should’ work. Lol.
Have you done any moisture testing? Is the salesperson going to do any moisture testing? Why would a salesperson jump straight to an epoxy moisture control system without even knowing what your slab is doing right now. What’s the CSP of your slab? You gonna shot blast your slab first to create a profile the epoxy can bond to? Are they just trying to be safe because the laminate is junk or the installers suck? Maybe make an additional sale by just selling you some crap you can roll on? Just questions that I have cus many salespeople I know don’t know much about concrete and moisture beyond the fact that concrete gives off residual moisture.
What kind of flooring is currently down now? Carpet? Bare concrete? Is this a basement? Any history of flooding?
Anyway, I would say most jobs don’t get any kind of moisture testing at all. Sad but that’s just how it is a lot of places. I guarantee you the instructions for your laminate floor have specific limitations on the amount of moisture in the substrate it is able to be installed over, both wood and concrete. Hopefully the installer has a moisture meter to check the slab at the time of installation. Is this DIY? Do you have a moisture meter or will you have someone else do moisture testing? Most jobs just get a 6 mil vapor barrier rolled out then whatever installed on top. Many LVP jobs don’t even get that anymore because there are some people believe the floor itself is ‘waterproof’ so therefore you don’t need a vapor barrier. The combo underlayments work but they have to be installed properly. Seams taped together or whatever else the instructions call for.
What products are you specifically looking at having installed? Have you checked your floor for flatness? Are you prepared to pay for subfloor prep if it doesn’t meet flatness specs as is called for by your choice of flooring. You got any pics? Man, I got questions.